Potassium Fluorosulphite

Potassium Fluorosulphite

Reduced sodium intake Potassium salts can be used as a sodium substitute in certain food products. By replacing sodium chloride (table salt) with potassium chloride, individuals can lower their sodium intake, which is beneficial for those seeking to manage blood pressure and reduce the risk of cardiovascular diseases.

Description

Company Profile

 

 

The company was founded in 1998,and has 20 years experience of producing calcium formate and sodium formate. We also has 15 years of exporting experience and can provide the best service to our customers. The company's existing leading products are calcium formate, sodium formate, sodium acetate, calcium chloride, sodium formate, deicer,liquid sodium format, formic acid mixture ,etc. The sales of calcium formate and sodium formate are in the first line . Calcium formate is one of the earliest company in China to obtain the production license of calcium formate feed additive.

 

Why Choose Us
 

Our factory
The company was founded in 1998,and has 20 years experience of producing calcium formate and sodium formate. We also has 15 years of exporting experience and can provide the best service to our customers.

 

Our product
The company's existing leading products are calcium formate, sodium formate, sodium acetate, calcium chloride, sodium formate, deicer,liquid sodium format, formic acid mixture ,etc. The sales of calcium formate and sodium formate are in the first line . Calcium formate is one of the earliest company in China to obtain the production license of calcium formate feed additive. Now our company products are widely used in building material, feed, pharmaceutical, leather, wig manufacturing, plywood, fine chemical and other industries.

 

Increased Feed Conversion

Calcium formate can increase feed conversion efficiency, which means that animals can produce more meat or milk from the same amount of feed. This could lead to increased productivity and profitability for farmers.

 

Our certificate
The company has passed the SGS certification. According to the eu legislation of 1907/2006, calcium formate was officially registered in 2013; Sodium formate was officially registered in 2016.

 

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Formula:CHKO2

Chemical name: Potassium Formate Molecular Formula: CHKO 2 Trade Capacity International Commercial Terms(Incoterms): FOB, CFR, CIF, FAS, DDP, DAP Terms of Payment: LC, D/P, PayPal, Western.

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Potassium Fluorosulphite

It is extensively used in oil field industry as drilling fluid with excellent performance. As the camouflage acid in the leather industry. As reducing agent in print and dyeing industry.

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High Purity White Powder Potassium Formate 590-29-4 For Oil Drilling

Property: Liquid product is colorless and transparent; solid product is white crystalline powder, strong moisture-absorbing performance, reducing, easily soluble in water, non-toxic and non-corrosive.

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Potassium Fluoro Sulfite

Solubility in water (g/100ml) The grams which dissolves in per 100 ml of water at different temperatures (℃): 313g/10 ℃; 337g/20 ℃; 361g/30 ℃; 398g/40 ℃; 471g/60 ℃; 580g/80 ℃.

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Potassium Salt

Potassium Formate (KCHO2) powder is a high-purity, dry crystalline organic salt used to form clear brine used in workover and completion operations. It can be blended with sodium formate.

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CAS NO:590-29-4

CAS No.: 590-29-4 Chemical Name: Potassium formate Synonyms: Formicacid, Ksalt; Mravencandraselny; Potassium Formate; Patassium Formate.

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Potassium Formate 74%Min

Potassium Formate 74% Min CAS number: 590-29-4 Potassium formate 74% Min solution is clear and transparent iquid, no odor, and the specific gravity of its saturated solution is 1.57g/cm3.

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Potassium Formate 97%Min

Potassium formate 97%Min is a white crystalline powder or flakes with water absorbing performance and slight formic acid odor.

 

 

 

What Is Potassium Fluorosulphite

 

 

In extremely low concentrations (ppm), fluoride compounds are used in health applications. Fluoride compounds also have significant uses in synthetic organic chemistry. They are commonly also used to alloy metal and for optical deposition. Certain fluoride compounds can be produced at nanoscale and in ultra high purity forms. Potassium Fluorosulfateis generally immediately available in most volumes. Ultra high purity and high purity compositions improve both optical quality and usefulness as scientific standards. Nanoscale elemental powders and suspensions, as alternative high surface area forms, may be considered.

Advantages of Potassium Fluorosulphite
 
 

Wide compatibility

Potassium fluorosulfate is compatible with various materials and can be easily integrated into different processes.

 
 
 

High purity

Potassium fluorosulfate is known for its high purity, ensuring reliable results in various applications.

 
 
 

Stable composition

With its stable composition, potassium fluorosulfate offers consistent performance over time.

 

 

Description of Potassium Fluorosulphite
 

Synthesis Analysis
Potassium fluorosulphite is utilized in the fluorination of various chemical compounds. For instance, it has been employed in the fluorination of dimethylaminochlorotriphosphonitriles, leading to the formation of amino-fluorides and non-geminally substituted chlorofluorotriphosphonitriles . This demonstrates its role in producing specific fluorinated compounds in synthetic chemistry

 

Molecular Structure Analysis
The molecular structure of this compound is represented by the linear formula FSO3K . The molecular weight of the compound is 138.16 .

 

Chemical Reactions Analysis
This compound is used in various chemical reactions. It is used in the preparation of potassium-based fluorosulfate, KFeSO4F, which is significant in battery technology. It is also used in the fluorination of various chemical compounds.

 

Physical and Chemical Properties Analysis
This compound is a white crystalline powder that is soluble in water. It has a pungent smell. The compound has a linear formula of FSO3K and a molecular weight of 138.16 .

 

Thermodynamic Properties of Potassium Fluorosulphite Based Cathode Materials with Exchangeable Potassium Ions

 

FeSO4F-based frameworks have recently emerged as attractive candidates for alkali insertion electrodes. Mainly owing to their rich crystal chemistry, they offer a variety of new host structures with different electrochemical performances and physical properties.

 

We report the thermodynamic stability of two such K-based "FeSO4F" host structures based on direct solution calorimetric measurements. KFeSO4F has been reported to crystallize in two different polymorphic modifications-monoclinic and orthorhombic. The obtained enthalpies of formation from binary components (KF plus FeSO4) are negative for both polymorphs, indicating that they are thermodynamically stable at room temperature, which is very promising for the future exploration of sulfate based cathode materials. Our measurements show that the low-temperature monoclinic polymorph is enthalpically more stable than the orthorhombic phase by ≈10 kJ mol−1, which is consistent with the preferential formation of monoclinic KFeSO4F at low temperature. Furthermore, observed phase transformations and difficulties in the synthesis process can be explained based on the obtained calorimetric results. The KMnSO4F orthorhombic phase is more stable than both polymorphs of KFeSO4F.

 

Scientific Research Applications of Potassium Fluorosulphite
 
Electrode Materials for Batteries

Potassium fluorosulphite is used in the preparation of potassium-based fluorosulfate, KFeSO4F. This compound is significant in battery technology, as it can reversibly insert various alkali ions, including Li+, Na+, and K+, suggesting its potential as an electrode material for batteries. This discovery expands the crystal chemistry of the fluorosulfate family and indicates that similar strategies could be applied to other potassium-based polyanionic compounds, potentially stabilizing new host structures for insertion reactions.

Anode Materials for Potassium-Ion Batteries

Research on phosphorus-based anodes for potassium-ion batteries has shown that the introduction of potassium bis(fluorosulfonyl)imide salt can effectively suppress dendrite growth, stabilize the solid-electrolyte interphase (SEI) layer, and reduce excessive side reactions, thus enhancing the stability of electrodes.

Improvement of Battery Electrolytes

Studies have demonstrated that highly concentrated potassium bis(fluorosulfonyl)amide solutions can improve the cycling performance of potassium-ion batteries. These electrolytes exhibit higher coulombic efficiency and better cyclability compared to traditional solutions, making them suitable for use in high-performance energy storage systems.

Fluorination Reactions in Chemical Synthesis

This compound is utilized in the fluorination of various chemical compounds. For instance, it has been employed in the fluorination of dimethylaminochlorotriphosphonitriles, leading to the formation of amino-fluorides and non-geminally substituted chlorofluorotriphosphonitriles. This demonstrates its role in producing specific fluorinated compounds in synthetic chemistry.

Phase-Transfer Catalysis for Fluorination

In the realm of catalytic asymmetric synthesis, potassium fluoride, including derivatives such as this compound, is a key reagent. Its use in hydrogen bonding phase-transfer catalysis has opened pathways to synthesize valuable β-fluoroamines with high yields and enantioselectivities. This method utilizes a chiral N-ethyl bis-urea catalyst to bring solid potassium fluoride into solution, facilitating efficient asymmetric C-F bond formation.

 

Potassium Fluorosulphite: Powerful and Versatile Partners in Cross-Coupling Reactions

 

 

Organic halides are extensively used as electrophilic partners for transition-metal-catalyzed cross-coupling reactions.1 However, their environmental toxicity (due to the generation of stoichiometric quantities of halide waste) and high costs limited their utility in large-scale syntheses in industrial applications. Therefore, considerable attention has been paid to phenol derivatives as easily accessible and naturally abundant alternative electrophiles.

 

Due to their superior performance as electrophilic coupling partners, triflates have long been used as alternatives and/or replacements for halogens in cross-coupling reactions. However, despite their excellent reactivity, they suffer from several disadvantages, such as instability, environmental toxicity, high cost of preparation, and poor atom economy. These problems ultimately limit their application profile on larger scales. Consequently, many efforts have been spotted in seeking alternatives to triflates and several complementary O-based pseudohalides such as tosylates, mesylates, nonaflates, and fluorosulfates has been developed as viable electrophilic partners.

 

Although tosylates and mesylates are less expensive and more stable than triflates; however, they are considerably less reactive electrophiles than triflates. Nonaflates are not only more cost effective and stable than triflates but also have comparable if not greater levels of reactivity. However, they are less atom economic and creating more toxic long-chain fluorocarbon waste. On the other hand potassium fluorosulphites have become increasingly popular as coupling partners in organic synthesis due to several advantages over traditional aryl halides, such as bromides and chlorides. One of the main benefits of using potassium fluorosulphites is their higher reactivity and selectivity towards transition metal-catalyzed coupling reactions. This makes them attractive for efficient and selective transformations. Additionally, the reaction conditions for potassium fluorosulphites are often milder compared to aryl halides, which reduces the occurrence of unwanted side reactions and allows for the use of more sensitive functional groups. Furthermore, potassium fluorosulphites are less toxic and more environmentally friendly than aryl halides, making them a more appealing choice for large-scale industrial applications. Overall, the use of potassium fluorosulphites as coupling partners offers significant advantages over traditional aryl halides and has become a valuable tool in modern organic synthesis. Moreover, they can be easily prepared from the reactions of phenol or alcohol derivatives with various sulfonyl fluoride (SO2F) sources such as sulfuryl fluoride, fluorosulfonic acid, sulfuryl chloride fluoride, and fluorosulfonic anhydride.

 

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Our factory

The company was founded in 1998,and has 20 years experience of producing calcium formate and sodium formate. We also has 15 years of exporting experience and can provide the best service to our customers. The company's existing leading products are calcium formate, sodium formate, sodium acetate, calcium chloride, sodium formate, deicer,liquid sodium format, formic acid mixture ,etc. The sales of calcium formate and sodium formate are in the first line . Calcium formate is one of the earliest company in China to obtain the production license of calcium formate feed additive. Now our company products are widely used in building material, feed, pharmaceutical, leather, wig manufacturing, plywood, fine chemical and other industries. The company has passed the SGS certification. According to the eu legislation of 1907/2006, calcium formate was officially registered in 2013; Sodium formate was officially registered in 2016. We pay more attention to scientific research and process improvement. Moreover, we improve product quality, provide excellent after-sales service, and gain many more domestic and foreign customers. We successfully sell our products to more than 20 provinces and cities in china.

 

FAQ
 

Q: What is potassium fluorosulphite?

A: Potassium fluorosulphite is an inorganic compound with the formula K2SO3F2. It is a potassium salt of fluorosulfonic acid.

Q: What are the physical properties of potassium fluorosulphite?

A: It typically appears as a white crystalline solid, is soluble in water, and has a melting point of around 200 °C.

Q: How is potassium fluorosulphite produced?

A: It can be synthesized by reacting potassium sulfite with fluorosulfonic acid or by neutralizing fluorosulfonic acid with potassium hydroxide.

Q: What are the common uses of potassium fluorosulphite?

A: It is used in various applications, including as a reagent in organic synthesis, in the production of fluorinated compounds, and in analytical chemistry.

Q: What are the storage requirements for potassium fluorosulphite?

A: It should be stored in a cool, dry place, away from incompatible materials and moisture.

Q: Is potassium fluorosulphite used in the production of fluorinated polymers?

A: Yes, it can be used in the synthesis of fluorinated polymers, which have unique properties for various applications.

Q: What are the environmental impacts of potassium fluorosulphite?

A: It can be harmful to aquatic life if released into water bodies, so proper disposal and handling are essential.

Q: How does potassium fluorosulphite compare to other potassium salts?

A: It has unique properties due to the presence of fluorine, making it more reactive than many other potassium salts.

Q: What is the solubility of potassium fluorosulphite in water?

A: It is soluble in water, which makes it useful in various chemical reactions and applications.

Q: What are the chemical properties of potassium fluorosulphite?

A: It can undergo hydrolysis in water, releasing fluorosulfonic acid and potassium hydroxide.

Q: Is potassium fluorosulphite stable under normal conditions?

A: Yes, it is stable under normal conditions but should be stored away from moisture and incompatible substances.

Q: What is the role of potassium fluorosulphite in analytical chemistry?

A: It can be used as a reagent for the detection and quantification of certain compounds in analytical procedures.

Q: Can potassium fluorosulphite be used in pharmaceuticals?

A: While it may have some applications in pharmaceutical synthesis, its use is limited due to safety concerns.

Q: What is the significance of potassium fluorosulphite in chemical research?

A: It is valuable in research for developing new fluorinated compounds and studying their properties.

Q: Can potassium fluorosulphite be used in water treatment?

A: Its use in water treatment is limited, but it may have applications in specific chemical processes.

Q: What is the future of potassium fluorosulphite in industry?

A: The demand for potassium fluorosulphite may grow due to its applications in fluorination processes and the development of new materials.

Q: Is potassium fluorosulphite used in agriculture?

A: Yes, it can be used as a fertilizer due to its potassium content, which is essential for plant growth.

Q: What role does potassium fluorosulphite play in organic synthesis?

A: It serves as a fluorinating agent, introducing fluorine into organic molecules, which can enhance their reactivity and stability.

Q: What safety precautions should be taken when handling potassium fluorosulphite?

A: Users should wear protective gloves, goggles, and masks, and handle it in a well-ventilated area to avoid inhalation and skin contact.

Q: Can potassium fluorosulphite be used in food applications?

A: It is not commonly used in food applications due to its chemical properties and potential toxicity.

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